Among the following compounds, the strongest acid is:
A
Cl-CH2-COOH
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B
H-COOH
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C
CH3-COOH
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D
CH3-CH2-COOH
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Solution
The correct option is ACl-CH2-COOH The halogenated fatty acids are much stronger acids than their parent fatty acids because of −I effect i.e. electron-withdrawing inductive effect.
−Cl is the second-highest electronegative element of the periodic table after F.
−C2H5 produces +I effect which decreases the acidic strength by increasing the negative charge on the carboxylate ion.