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Question

Among the following compounds which has the highest boiling point?

A
2-Bromopentane
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B
3-Bromopentane
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C
1-Bromopentane
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D
All have same boiling point
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Solution

The correct option is D 1-Bromopentane
For Alkyl halides containing same halide, the boiling point increases with increase in size of the Alkyl group. Thus I-bromopentane has more boiling point than 2-bromo and 3-bromo pentan.

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