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Question

Among the following compounds, which one of the following will react with acetone to give product containing >C=N group ?
C6H5NH2, (CH3)3N, C6H5NHC6H5, C6H5NHNH2

A
(CH3)3N, C6H5NHC6H5
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B
C6H5NH2, (CH3)3N
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C
C6H5NH2, C6H5NHNH2
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D
(CH3)3N, C6H5NHNH2
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Solution

The correct option is C C6H5NH2, C6H5NHNH2
For the compound to react with acetone, it must contain a NH2 group which react with acetone to give a product containing >C=N.
Here, C6H5NH2 and C6H5NHNH2 are the compound that have NH2 group.
C6H5NH2+O=C(CH3)2+H+C6H5N=C(CH3)2+H2O Amine Imine (Schiff's Base)
C6H5NHNH2+O=C(CH3)2+H+C6H5NHN=C(CH3)2+H2O Phenylhydrazine Phenylhydrazone
Thus, the correct answer is option (c).

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