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Linear Combination of Atomic Orbitals

Among the fol...

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Among the following molecular orbitals , how many have at least one nodal plane ? sigma* 1s, sigma 2s, sigma2pz, 2px , 2py, sigma 2pz

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Q. How many orbitals are having higher energy compared to

σ_{2 S}

L i_{2}

molecule from the molecular orbitals given below.

σ^{*} 1 s, σ^{*} 2 s, σ 1 s, π 2 p_{y}, π^{*} 2 p_{x}, π^{*} 2 p_{z}, π 2 p_{z}

Q. The relative energies of molecular orbitals are found to be in increasing order as follows-

σ (1 s) < σ^{*} (1 s) < σ (2 s) < σ^{*} (2 s) < [π (2 p_{y}) π (2 p_{z})] < σ (2 p_{x}) < [π^{*} (2 p_{y}) π^{*} (2 p_{z})] < σ^{*} (2 p_{x})

x -

axis as the internuclear axis, the overlap of which of the following orbitals will not form a sigma bond and why?

1 s

2 s

1 s

2 p_{x}

2 p_{y}

2 p_{y}

1 s

2 s

Q. How many nodal plane is/are present in

σ_{p - p}

bonding molecular orbital ?

Q. How many nodal plane is/are present in

σ_{s - s}^{*}

anti- bonding molecular orbital ?

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