Among the following molecules, the correct order of C−C bond length is:
A
C2H6>C2H4>C6H6>C2H2
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B
C2H6>C6H6>C2H4>C2H2(C6H6 is benzene)
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C
C2H4>C2H6>C2H2>C6H6
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D
C2H6>C2H4>C2H2>C6H6
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Solution
The correct option is CC2H6>C6H6>C2H4>C2H2(C6H6 is benzene) Ethane contains carbon-carbon single bond. Benzene is aromatic in nature. It has resonance. All the carbon-carbon bonds in benzene have partial double bond character. Ethylene contains carbon-carbon double bond. Acetylene contains carbon-carbon triple bond. The order of bond length is, single bond>partial double bond> double bond > triple bond. Hence, the correct order of carbon-carbon bond length is C2H6>C6H6>C2H4>C2H2.