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Question

Among the following pair of compounds, the one that illustrates the law of multiple proportions is:

A
NH3 and NCl3
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B
H2S and SO2
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C
CS2 and FeSO4
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D
CuO and Cu2O
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Solution

The correct option is D CuO and Cu2O
The law of multiple proportions, states that when two elements combine with each other to form more than one compound, the weights of one element that combine with a fixed weight of the other are in a ratio of small whole numbers.
In CuO and Cu2O, the O:Cu is 1:1 and 1:2. Hence, this combination of molecules follows law of multiple proportions

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