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Question

Among the following, select the correct statements.
I) PH5 does not exist.
II) pπdπ bond is present in SO24.
III) SeF4 and CH4 have the same shape.
IV) I+3 has a bent shape.

A
II, III
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B
I, II
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C
I, IV
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D
I, II, IV
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Solution

The correct option is D I, II, IV
PH5 does not exist because the energy difference between d- and s-orbitals of P and H, respectively is very high.
pπdπ bond is present in SO24 due to overlapping of fully occupied p-orbitals of O with empty d-orbitals of S.
I+3 has a bent shape due to presence of two lone pair of electrons.

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