Among the following- select the correct statements-I PH5 does not exist-II p -d- bond is present in SO2-4-III SeF4 and CH4 have the same shape-IV I-3 has a bent shape-

The correct option is D I, II, IV PH_5 does not exist because the energy nbsp;difference between d and s orbitals of P and H, respectively is very high ...

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Among the fol...

Question

Among the following, select the correct statements.
I) ${P H}_{5}$ does not exist.
II) $p π - d π$ bond is present in ${S O}_{4}^{2 -}$ .
III) $S e F_{4}$ and $C H_{4}$ have the same shape.
IV) $I_{3}^{+}$ has a bent shape.

II, III

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I, II

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I, IV

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I, II, IV

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Solution

The correct option is D I, II, IV
$P H_{5}$ does not exist because the energy difference between d- and s-orbitals of P and H, respectively is very high.
$p π - d π$ bond is present in ${S O}_{4}^{2 -}$ due to overlapping of fully occupied p-orbitals of O with empty d-orbitals of S.
$I_{3}^{+}$ has a bent shape due to presence of two lone pair of electrons.

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Similar questions

Q. Which of the following statements is/are true?
1)

P H_{5}

and

B i C l_{5}

do not exist.
2)

p π - d π

bond is present in

S O_{2}

.
3)

I_{3}^{+}

has bent geometry.
4)

S e F_{4}

and

C H_{4}

have same shape.

Q. Which are true statements among the following ?
(A)

P H_{5}

and

B i C l_{5}

do not exist
(B) Bond order of

C O_{3}^{2 -}

is 1.33
(C)

S e F_{4} a n d C H_{4}

have same shape
(D)

I_{3}^{+}

has bent geometry
(E) The number of

P_{π} - d_{π}

bonds in

S O_{2} & S O_{3}

are same

Q. Which are true statements among the following?
(1)

{P H}_{5}

and

B i {C l}_{5}

do not exist
(2)

p π - d π

bonds are present in

S O_{2}

(3) Electrons travel with speed of light
(4)

S e F_{4}

and

{C H}_{4}

has same shape
(5)

I_{3}^{+}

has bent geometry

Which are true statements among the following ?

(A) $P H_{5}$ and $B i C L_{5}$ do not exist

(B) Bond order of $C O_{3}^{- 2}$ is 1.33

(D) $I_{3}^{+}$ has bent geometry

(E) The number of $P_{π} - d_{π}$ bonds in $S O_{2} & S O_{3}$ are same

Which are true statements among the following ?

(A) $P H_{5}$ and $B i C l_{5}$ do not exist

(B) Bond order of $C O_{3}^{-} 2$ is 1.33

(D) $I_{3}^{-}$ has linear geometry

(E) The number of $P_{π}$ - $d_{π}$ bonds in $S O_{2}$ and $S O_{3}$ are same

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Among the following, select the correct statements.I) PH5 does not exist.II) pπ−dπ bond is present in SO2−4.III) SeF4 and CH4 have the same shape.IV) I+3 has a bent shape.

Among the following, select the correct statements.
I) ${P H}_{5}$ does not exist.
II) $p π - d π$ bond is present in ${S O}_{4}^{2 -}$ .
III) $S e F_{4}$ and $C H_{4}$ have the same shape.
IV) $I_{3}^{+}$ has a bent shape.