The correct options are
C zinc blende and pyrites are sulphides of Cu
D malachite and azurite are sulphate ores of Cu
(A) Calamine is ZnCO3 and Cerussite is PbCO3. Thus, option A is correct.
(B) Rutile is TiO2. Cuprite (Ruby copper) is Cu2O.
Thus, option B is correct.
(C) Zinc blend is ZnS. Copper pyrite is CuFeS2.
Thus, option C is incorrect.
(D) Malachite is Cu(OH)2.CuCO3 and Azurite is Cu(OH)2.2CuCO3.