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Question

Among the following, the diamagnetic compound is/ are:

A
Na2O2
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B
O3
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C
N2O
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D
KO2
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Solution

The correct options are
B Na2O2
C N2O
D O3
If the number of electrons is even, then the molecule is usually diamagnetic - If all the electrons are paired.
A) Na2O2 (11×2+8×2=38 even number of electrons), so diamagnetic.
B) O3 (3×8=24 even number of electrons), so diamagnetic.
C) N2O (2×7+8=22 even number of electrons), so diamagnetic.
D) KO2 (19+2×8=35 odd number of electrons), so paramagnetic.
Hence options A,B and C are correct.

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