Among the following the least thermally stable is-

K₂CO₃

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Na₂CO₃

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BaCO₃

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Li₂CO₃

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Solution

The correct option is D
Li₂CO₃

Among $L i^{+}, N a^{+}, K^{+} a n d B a^{2 +}, L i^{+}$ has the smallest size and hence has the highest polarizing power. As a result, $L i_{2} C O_{3}$ has the least ionic character and hence has the least stability.

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L i_{2} C O_{3}, R b_{2} C O_{3}, C s_{2} C O_{3}, N a_{2} C O_{3}, K_{2} C O_{3}

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