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Question

Among the following, the maximum covalent character is shown by which compound?

A
FeCl2
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B
SnCl2
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C
AlCl3
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D
MgCl2
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Solution

The correct option is A AlCl3
As the cation charge increases, the covalent character also increases.

According to Fajans rule, cation with greater charge and smaller size favour covalency.

All the central metals have +2 oxidation except for Al which has +3 oxidation state.

Hence, Al shows more covalent character as compared to others.

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