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Question

Among the following, the number of compounds which do not hydrolyze

NF3,NCl3,PCl3,PCl5,CCl4,SiCl4,BiCl3,NaCl,FeCl3

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Solution

NF3,CCl4,NaCl do not hydrolyze
NF3, CCl4 - does not have a vacant d-orbital
NaCl - Salts of strong acid and strong base do not undergo hydrolysis they just get solvated in the solution.

NCl3H2ONH4OH+HOClPCl3H2OH3PO3+HClPCl5H2OH3PO4+HClSiCl4H2OH2SiO3+HClBiCl3H2OBiOCl+HClFeCl3H2OFe(OH)3+H++Cl


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