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Question

Among the halides, (i) -BCl3, (ii) −AlCl3 (iii) −GaCl3 (iv) −TlCl3. The order of lewis acidic nature is :

A
(i) > (ii) > (iii)>(iv)
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B
(ii) > (i) >(iii) > (iv)
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C
(iv) > (iii) > (ii) > (i)
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D
(iv) > (i) > (ii) > (iii
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Solution

The correct option is A (i) > (ii) > (iii)>(iv)
The order of lewis acidic nature is (i)BCl3>(ii)AlCl3>(iii)GaCl3>(iv)TlCl3
As the atomic number increases, the acidic character decreases.

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