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Byju's Answer
Standard XII
Chemistry
Crystal Field Split in Octahedral Complexes
Among the lig...
Question
Among the ligands
N
H
3
,
e
n
,
C
N
−
and
C
O
, the correct order of their increasing field strength is?
A
N
H
3
<
e
n
<
C
N
−
<
C
O
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B
C
N
−
<
N
H
3
<
C
O
<
e
n
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C
e
n
<
C
N
−
<
N
H
3
<
C
O
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D
C
O
<
N
H
3
<
e
n
<
C
N
−
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Solution
The correct option is
B
N
H
3
<
e
n
<
C
N
−
<
C
O
Increasing order of field strength is
N
H
3
<
e
n
<
C
N
−
<
C
O
.
In general, field strength order is Halogen family
<
Oxygen family
<
Nitrogen family
<
Carbon family.
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Among the ligands
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the correct order of their increasing field strength, is
Q.
49.No of co ordination isomers of [Cr(NH3)6][Co(CN)6] and[Cr(en)3][Co(CN)6] Are?
Q.
Q 3. Stability constant is maximum for:
(a) [Co (NH3)6]2+ (b) [Co(CN)6]4-
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12. Correct increasing order for the wavelengths of absorption in the visible region for the complexes of Co3+ is (1) [Co(en)3]3+, [Co(NH3)6]3+, [Co(H2O)6]3+ (2) [Co(H2O)6]3+, [Co(en)3]3+[Co(NH3)6]3+ (3) [Co(H2O)6]3+, [Co(NH3)6]3+, [Co(en)3]3+ (4) [Co(NH3)6]3+, [Co(en)3]3+, [Co(H2O)6]3+
Q.
The complex having highest stability among the following is \lbrack Co(CN)6\rbrack3–, \lbrack Fe(H2O)6\rbrack3+, \lbrack Co(en)3\rbrack3+ ,\lbrack Cr(NH3)6\rbrack3+
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