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Question

Amongst the following ions which one has the highest magnetic moment value?

(i) [Cr(H2O)6]3+ (ii) [Fe(H2O)6]2+ (iii) [Zn(H2O)6]2+

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Solution

The oxidation states of metals in the complexes along with the electronic configuration are given:
Cr3+ :3d3 configuration; no. of unpaired electrons (n) = 3
Fe2+ :3d6 configuration; n = 4
Zn2+ :3d10 configuration; n = 0
The complex [Fe(H2O)6]2+ with maximum number of unpaired electrons has the highest magnetic moment.


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