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Question

An acid-base indicator has Ka=3.0×105. The acid form ofthe indicator is red and the basic form is blue. Then pH is ___________ when indicator is 75% blue.

A
5
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B
4
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C
9.8
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D
10.2
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Solution

The correct option is D 5
As we know,

pH=pKIn+log[In]/[HIn]

so when the indicator is 75% red.

pH=pKIn+log[In]/[HIn]=5log3+log0.25/0.75=4.04

and when the indicator is 75% blue.

pH=pKIn+log[In]/[HIn]=5log3+log0.75/0.25=5

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