The correct option is C 100 mL of 0.1 M HCl and 200 mL of 0.1 M CH3COONa
A buffer solution is an aqueous solution consisting of a mixture of a weak acid and its conjugate base, or vice versa.
HCl+CH3COONa→CH3COOH+NaCl
10 mmol 20 mmol − −
− 10 mmol 10 mmol 10 mmol (after reaction)
So, finaly we get mixture of
CH3COOH+CH3COONa that will work like acidic buffer solution.
Hence, option (c) only act as acid buffer.