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Question

An acid buffer is obtained on mixing :

A
100 mL of 0.1 M CH3COOH and 200 mL of 0.1 M NaOH
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B
100 mL of 0.1 M CH3COOH and 100 mL of 0.1 M NaOH
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C
100 mL of 0.1 M HCl and 200 mL of 0.1 M CH3COONa
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D
100 mL of 0.1 M HCl and 200 mL of 0.1 M NaCl
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Solution

The correct option is C 100 mL of 0.1 M HCl and 200 mL of 0.1 M CH3COONa
A buffer solution is an aqueous solution consisting of a mixture of a weak acid and its conjugate base, or vice versa.

HCl+CH3COONaCH3COOH+NaCl
10 mmol 20 mmol
10 mmol 10 mmol 10 mmol (after reaction)

So, finaly we get mixture of
CH3COOH+CH3COONa that will work like acidic buffer solution.

Hence, option (c) only act as acid buffer.

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