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Carbohydrates

An aldehyde, ...

Question

An aldehyde, ( P) which does not undergo self aldol condensation gives benzaldehyde and two moles of ( Q) on ozonolysis. Compound ( Q), on oxidation with silver ions gives oxalic acid. The structure of ( P) is given as

A

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B

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C

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D

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Solution

The correct option is B

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Q. A compound A with molecular formula

C_{10} H_{13} C l

gives a white precipitate on adding silver nitrate solution. A on reacting with alcoholic KOH gives compound B as the main product. B on ozonolysis gives C and D. C gives Cannizaro reaction but not alodol condensation. D gives aldol condensation but not Cannizaro reaction. A is:

Q. A compound A with molecular formula

C_{10} H_{13} C l

gives a white precipitate on adding silver nitrate solution. A on reacting with alcoholic KOH gives compound B as the main product. B on ozonolysis gives C and D. C gives Cannizaro reaction but not alodol condensation. D gives aldol condensation but not Cannizaro reaction. A is:

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B (C_{6} H_{12})

C (C_{6} H_{14})

A

on ozonolysis followed by hydrolysis gives two aldehydes

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E (C_{2} H_{2 -} O_{2})

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K M n O_{4}

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C_{5} H_{10} O (A)

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Q. Assertion :Benzaldehyde does not undergoes aldol condensation. Reason: Benzaldehyde does not contain acidic

α

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