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Question

An alkane with molecular formula C5H12 forms only one monochloro product when heated with Cl2. The IUPAC name of this compound is:

A
1,1-dimethyl propane
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B
1,2-dimethyl propane
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C
2,2-dimethyl propane
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D
none of the above
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Solution

The correct option is D 2,2-dimethyl propane
The IUPAC name of the alkane is 2,2-dimethyl propane.
In this compound, all the hydrogen atoms are identical.
Hence, on monochlorination, only one product will be obtained.
On monochlorination, it forms 1-chloro-2,2-dimethylpropane.
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