An amount Q of heat is added to a monoatomic ideal gas in a process in which the gas performs a work of Q2 on its surrounding. Find equation of the process that monoatomic gas is undergoing.
A
PV23=constant
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B
PV43=constant
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C
PV13=constant
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D
PV35=constant
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Solution
The correct option is CPV13=constant Given ΔW=Q2
From first law of thermodynamics ΔQ=ΔU+ΔW ⇒ΔU=Q2 ∴dU=dW ⇒nCVdT=PdV ⇒(nRγ−1)dT=PdV
We know that for monoatomic gas γ=53,
using PV=nRT, we get, PdV+VdP=nRdT ⇒32(PdV+VdP)=PdV(∵γ=53) ⇒PdV+3VdP=0 ⇒dVV+3dPP=0 ⇒VP3=constant ⇒PV13=constant