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Question

An analysis of Pyrex glass showed the presence of 12.9% of B2O3, 2.2% of Al2O3, 3.8% of Na2O, 0.4% of K2O and the remaining was SiO2. What is the ratio of silicon to boron atoms in the glass?

A
1:7.3
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B
3.65:1
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C
1:4.3
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D
4.3:1
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Solution

The correct option is B 3.65:1
Let us assume 100 g pyrex glass
Percentage of B2O3=12.9%
Mass of B2O3=12.9 g
Percentage of SiO2=100[12.9+2.2+3.8+0.4]=80.7%
Mass of SiO2=80.7 g
Number of moles of B2O3=MassMolar mass=12.970=0.184
Number of moles of boron atoms =2×0.184
Number of moles of SiO2=MassMolar mass=80.760=1.345
Number of moles of silicon atoms =1.345
Number of atoms of siliconNumber of atoms of boron=NA×1.345NA×0.184×2=3.651
Where, NA = Avogadro′s number

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