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Question

An aqueous solution containing 2.14 g KIO3 was treated with 100 ml of 0.4MKI solution, the weight of I2 produced is :

A
6.096 g
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B
7.620 g
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C
30.480 g
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D
18.288 g
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Solution

The correct option is A 6.096 g
2.14 g of KIO3 corresponds to 2.14214=0.01 moles.
100 ml of 0.4MKI solution corresponds to 1001000×0.4=0.04 moles.
0.001 moles of KIO3 will give 0.005 moles of KI.
However, only 0.04 moles of KI are present.
Thus, KI is the limiting reagent.
Mass of iodine obtained is 0.04×35×254=6.096 g.

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