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Question

An aqueous solution of an inorganic compound (X) gives the following reactions.

(i)
With an aqueous solution of BaCl2, a precipitate insoluble in dilute HCl is obtained.

(ii) Addition of excess of KI gives a brown precipitate which turns white on addition of excess hypo solution.

(iii)
With an aqueous solution of potassium ferrocyanide a chocolate colored ppt. is obtained.

Identify X :

A
CuSO4
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B
BaSO4
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C
BaCl
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D
NaI
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Solution

The correct option is B CuSO4
Reaction Process:

(i) CuSO4+BaCl2BaSO4+2HCl
(ii) 2CuSO4+4KI2K2SO4+CuI2+I2Whiteppt.
(iii) 2Cu2++K4[Fe(CN)6]Cu2[Fe(CN)6]+4K+Redbrown(chocolate)ppt.

Therefore, from the above reaction, option A is correct.

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