Question
An aqueous solution of NaCl on electrolysis gives H2(g), Cl2(g) and NaOH according to reaction,
2Cl−(aq)+2H2O→2OH−(aq)+H2(g)+Cl2(g)
A direct current of 25 ampere with a current efficiency of 62% is passed through 20 litre of NaCl solution (20% by mass) Write down the reactions taking place at the electrodes.
The redox changes are : Cathode: 2Cl−→Cl2+2e
Anode : 2e+2H2O→2OH−+H2