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Question

An aqueous solution of NaCl on electrolysis gives H2(g), Cl2(g) and NaOH according to reaction,
2Cl(aq)+2H2O2OH(aq)+H2(g)+Cl2(g)
A direct current of 25 ampere with a current efficiency of 62% is passed through 20 litre of NaCl solution (20% by mass) Write down the reactions taking place at the electrodes.
The redox changes are : Cathode: 2ClCl2+2e
Anode : 2e+2H2O2OH+H2

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Solution

The redox changes are : Anode: 2ClCl2+2e Cathode : 2e+2H2O2OH+H2

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