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Question

An aqueous solution of sucrose, C12H22O11, containing 34.2 g/L has an osmotic pressure of 2.38 atmospheres at 17oC, For an aqueous solution of glucose, C6H12O6, to be isotonic, with this solution, it would have:

A
34.2 g/L of glucose
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B
17.1 g/L of glucose
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C
18.0 g/L of glucose
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D
36.0 g/L of glucose
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Solution

The correct option is C 18.0 g/L of glucose
we have,
π=CRT
strength of sucrose solution = 34.2 g/L

molar mass of sucrose = 342

molar mass of glucose = 180

since both solution are isotonic, we have

C1RT=C2RT

34.2342=M180

we get M=18g/L

strength of glucose solution = 18g/L

Hence, option (C) is correct.

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