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Polyhalogen Compounds

An aromatic a...

Question

An aromatic amine (A) was treated with alcoholic potash and another compound (Y) when a foul smelling gas was formed with formula $C_{6} H_{5} N C .$ (Y) was formed upon reaction of a compound (Z) with $C l_{2}$ in the presence of slaked lime. Identify compound (Z) from the following options.

C_{6} H_{5} N H_{2}

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C H_{3} O H

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C H_{3} C O C H_{3}

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C H C l_{3}

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Solution

The correct option is C $C H_{3} C O C H_{3}$
$C_{6} H_{5} N H_{2} + K O H + (Y) \to C_{6} H_{5} N C$ ;
(Y) is $C H C l_{3}$ ; (Y) is formed from (Z)+ $C l_{2} + C a (O H)_{2}$ and thus, (Z) is $C H_{3} C O C H_{3}$ .

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