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Question

An endothermic reaction which proceeds with decrease in volume will give maximum yield of the products at high P and high T .
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Solution

An endothermic reaction which proceeds with decrease in volume will give maximum yield of the products at high P and high T .
Since the reaction proceeds with decrease in volume, at high pressure, the equilibrium will shift in the forward direction which will reduce the effect of high temperature. The endothermic reaction absorbs heat. When temperature is high, the equilibrium will shift in the forward direction so as to reduce the effect of high temperature. Hence, under the conditions of high temperature and high pressure, the yield of the reaction will be maximum.

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