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Question

An equilibrium mixture for the reaction: 2H2S(g)2H2(g)+S2(g) had 1 mole of H2S, 0.2 mole of H2 and 0.8 mole of S2 in 2 L flask. The value of Kc in mol.lit1 is;

A
0.004
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B
0.08
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C
0.016
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D
0.16
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Solution

The correct option is D 0.016
The equilibrium reaction is 2H2S(g)2H2(g)+S2(g).

The expression for the equilibrium constant is Kc=[H2]2[S2][H2S]2

The number of moles of H2S,H2 and S2 in the equilibrium mixture are 1,0.2 and 0.8 respectively.

The volume of the flask is 2 L.

Hence, the molar concentrations of H2S, H2 and S2 in the equilibrium mixture are 0.5,0.1 and 0.4 respectively.

Substitute the values in the expression for the equilibrium constant.
Kc=(0.1)2×0.4(0.5)2=0.016

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