An equimolar mixture of toluene and chlorobenzene is treated with a mixture of $conc. H_{2} S O_{4}$ and $conc. H N O_{3}$ . Indicate the correct statement from the following:

p-nitrotoluene is formed in excess

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equimolar amounts of p-nitrotoluene and p-nitrochlorobenzene are formed

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p-nitrochlorobenzene is formed in excess

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m-nitrochlorobenzene is formed in excess

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Solution

The correct option is A p-nitrotoluene is formed in excess
As toluene and chlorobenzene, both can react with mixture of $c o n c . H_{2} S O_{4}$ and $c o n c . H N O_{3}$ , but being more reactive, toluene will yield p-nitrotoluene in excess.

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How will you convert benzene into

(i) p-nitrobromobenzene (ii) m-nitrochlorobenzene

(iii) p -nitrotoluene (iv) acetophenone

How will you convert benzene into
(i) p-nitrobromobenzene

(ii) m-nitrochlorobenzene

(iii) p -nitrotoluene

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Q. An ethereal solution of 4-nitrochlorobenzene is treated with metallic sodium. The product formed is:

Arrange the following set of compounds in order of their decreasing relative reactivity with an electrophile, E⁺

(a) Chlorobenzene, 2,4-dinitrochlorobenzene, p-nitrochlorobenzene

(b) Toluene, p-H₃C–C₆H₄–NO₂, p-O₂N–C₆H₄–NO₂.

Arrange the following set of compounds in order of their decreasing relative reactivity with an electrophile, $E^{+}$
(a)Chlorobenzene, 2,4-dinitrochlorobenzene, p-nitrochlorobenzene

(b)Toluene, $p - H_{3} C - C_{6} H_{4} - N O_{2}, p - O_{2} N - C_{6} H_{4} - N O_{2} .$

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An equimolar mixture of toluene and chlorobenzene is treated with a mixture of conc.H2SO4 and conc.HNO3. Indicate the correct statement from the following:

The correct option is A p-nitrotoluene is formed in excessAs toluene and chlorobenzene, both can react with mixture of conc.H2SO4 and conc.HNO3, but being more reactive, toluene will yield p-nitrotoluene in excess.

An equimolar mixture of toluene and chlorobenzene is treated with a mixture of $conc. H_{2} S O_{4}$ and $conc. H N O_{3}$ . Indicate the correct statement from the following:

The correct option is A p-nitrotoluene is formed in excess
As toluene and chlorobenzene, both can react with mixture of $c o n c . H_{2} S O_{4}$ and $c o n c . H N O_{3}$ , but being more reactive, toluene will yield p-nitrotoluene in excess.