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Question

An ether is more volatile than an alcohol having the same molecular formula. This is due to which of the following?

A
Alcohols having resonance structures
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B
Inter-molecular hydrogen bonding in alcohols
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C
Inter-molecular hydrogen bonding in ethers
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D
Dipolar character of ethers
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Solution

The correct option is C Inter-molecular hydrogen bonding in alcohols
An ether is more volatile than an alcohol having the same molecular formula. This is due to inter-molecular hydrogen bonding in alcohols. The inter-molecular hydrogen bonding in alcohols leads to molecular association and raises boiling point. Due to this, alcohol becomes less volatile. The inter-molecular hydrogen bonding is not possible in ethers as in ethers, H atom is not attached to electronegative O atom.

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