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Question

An experiment is carried on a fixed amount of gas at different temperatures and at high pressure such that it deviates from the ideal gas behaviour. The variation of (PVRT) with particle is shown in the figure. The correct variation will correspond to?
141543_6ea119ade7d44bfdb00ada2545c56838.png

A
curve A
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B
curve B
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C
curve C
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D
curve D
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Solution

The correct option is B curve B
At low pressure, the gas will show ideal behaviour and hence PVRT=numberofmoles which will remain constant.
But as pressure increases, there will be dominant interatomic forces and actual volume will be less due to finite size. Hence, B curve will be followed.

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