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Question

An experiment showed that in a lead chloride solution, 6.21 g of lead combined with 4.26 g of chlorine.

What is the empirical formula of this chloride? [Pb = 207, Cl = 35.5]


A

PbCl2

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B

PbCl3

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C

PbCl4

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D

PbCl6

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Solution

The correct option is C

PbCl4


Element% compositionAt. Wt.Atomic ratioSimplest At. ratioPb6.2110.47×100=59.31 %20759.31207=0.2860.2860.286=1Cl4.2610.47×100=40.69 %35.540.6935.5=1.1461.1460.286=4

Hence, the empirical formula of the compound is PbCl4.


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