An ideal gas expands against a constant external pressure of 2.0 atmosphere from 20 litre to 40 litre and absorbs 10kJ of heat from surrounding. What is the change in internal energy of the system? (Given : 1 atm litre =101.3J)
A
4052J
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B
5948J
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C
14052J
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D
9940J
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Solution
The correct option is B5948J Here gas is expanded against constant pressure. So, it is a irreversible system. ∴ work done =−P×ΔV ⇒w=−2atm×20Litre =−40atm.Litre=−40×101.3J=−4052J ΔU=q+w =10×1000−4052=5948J