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Question

An ideal gas expands against a constant external pressure of 2 atmosphere from 20 litre to 40 litre and absorbs 10 KJ of heat from surrounding. What is the change in internal energy of the system?

A
4052 J
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B
5948 J
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C
14052 J
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D
9940 J
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Solution

The correct option is A 14052 J
ΔH=ΔU+W
expansion P1V1=P2V2
P1=P2=2atm=2×1.0132×105 Pa
V1=2ol=20×103m3
V2=4ol=40×103m3

P1V1=P2V2=2×1.0132×20×102
=4.0528×103

ΔU=10KJ+4.0528KJ
ΔU=14052J

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