An ideal gas having initial pressures P, volume V and temperature R is allowed to expand adiabatically until its volume becomes 5.66V while its temperature falls to T/2. How many degrees of freedom do the gas molecules have?
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Solution
For an adiabatic change (V′V)(gamma−1)=TT′ Given V′=5.66V and T′=T2. ⇒(5.66)(γ−1)=2 (γ−1)log(5.66)=log(2)
⇒γ=1+log(2)log(5.66)=1+0.30100.7528=1+0.4=1.4
Since γ=1.4, the gas is diatomic. For a diatomic gas, the number of degrees of freedom of the molecules =5.