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Question

An ideal gas is enclosed in a cylinder with a movable piston on top. The piston has mass of 8000 gm and an area of 5.00cm2 and is free to slide up and down, Keeping the pressure of the gas constant. How much work is done (in J) as the temperature of 0.200 mol of the gas is raised from 200oCto300oC

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Solution

The first law of thermodynamics gives us the relation:
δq=ΔU+w
δq=nCdT where C is the specific heat capacity for the process and n is the no of moles of the ideal gas.
Here, the process is a constant pressure process, hence C=Cp
And the change in internal energy for an ideal gas is given by nCvdT.
i.e.
nCpdT=nCvdT+w
n(CpCv)dT=w ; CpCv=R for an ideal; R (universal gas constant)
i.e. w=nRdT=nR(T2T1)=0.2×8.314×(300200)=0.2×8.314×100=166J

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