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Byju's Answer
Standard XII
Chemistry
Heat Capacity
An ideal gas ...
Question
An ideal gas undergoes a cyclic process as shown in Figure.
Δ
U
B
C
=
−
5
kJ
m
o
l
−
1
,
q
A
B
=
2
kJ
m
o
l
−
1
W
A
B
=
−
5
kJ
m
o
l
−
1
,
W
C
A
=
3
kJ
m
o
l
−
1
Heat absorbed by the system during process CA is:
A
+
18
kJ
m
o
l
−
1
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B
−
18
kJ
m
o
l
−
1
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C
−
5
kJ
m
o
l
−
1
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D
+
5
kJ
m
o
l
−
1
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Solution
The correct option is
D
+
5
kJ
m
o
l
−
1
Δ
U
A
B
=
q
A
B
+
W
A
B
=
2
+
(
−
5
)
=
−
3
k
J
/
m
o
l
Δ
U
B
C
=
−
5
k
J
/
m
o
l
For cyclic process,
Δ
U
=
0
Δ
U
A
B
+
Δ
U
B
C
+
Δ
U
C
A
=
0
Δ
U
C
A
=
−
Δ
U
A
B
−
Δ
U
B
C
Δ
U
C
A
=
−
(
−
3
)
−
(
−
5
)
=
8
k
J
/
m
o
l
Δ
U
C
A
=
q
C
A
+
W
C
A
8
=
q
C
A
+
3
q
C
A
=
+
5
k
J
/
m
o
l
Heat absorbed has positive sign.
Suggest Corrections
0
Similar questions
Q.
What is the heat of formation of liquid methyl alcohol in
k
J
m
o
l
−
1
,
use the following data.
Heat of vaporization of liquid methyl alcohol =
38
k
J
m
o
l
−
1
.
Heat of formation of gaseous atoms from the elements in their standard states:
H
=
218
k
J
m
o
l
−
1
,
C
=
715
k
J
m
o
l
−
1
,
O
=
249
k
J
m
o
l
−
1
Average bond energies :
C
−
H
=
415
k
J
m
o
l
−
1
C
−
O
=
356
k
J
m
o
l
−
1
O
−
H
=
463
k
J
m
o
l
−
1
Q.
Calculate the lattice enthalpy of
C
a
C
l
2
, given that :
Enthalpy of sublimation for
C
a
(
s
)
→
C
a
(
g
)
=
121
k
J
m
o
l
−
1
Enthalpy of dissociation of
C
l
2
(
g
)
→
2
C
l
(
g
)
=
242.8
k
J
m
o
l
−
1
Ionisation energy of
C
a
(
g
)
→
C
a
+
+
(
g
)
=
2422
k
J
m
o
l
−
1
Electron gain enthalpy of
2
C
l
→
2
C
l
−
1
=
(
2
×
−
355
)
k
J
m
o
l
−
1
=
−
710
k
J
m
o
l
−
1
Enthalpy of formation of
C
a
C
l
2
=
−
795
k
J
m
o
l
−
1
Q.
What is the work which could be obtained from an isothermal reversible expansion of
1
m
o
l
of
C
l
2
from 1
d
m
3
to 50
d
m
3
at
273
K
using ideal gas behaviour
(Given
l
o
g
5
=
0.693
)
Q.
Calculate the resonance energy of
N
2
O
from the following data:
△
f
H
o
o
f
N
2
O
=
82
k
J
m
o
l
−
1
,
N
≡
N
,
946
k
J
m
o
l
−
1
;
N
=
N
,
418
k
J
m
o
l
−
1
;
O
=
O
,
498
k
J
m
o
l
−
1
;
N
=
O
,
607
k
J
m
o
l
−
1
Q.
What is the heat of solution of sodium chloride if hydration energy of
N
a
+
is
−
389.4
kJ mol
−
1
, hydration energy of
C
l
−
is
−
382.3
kJ mol
−
1
and lattice energy of
N
a
C
l
=
+
776
kJ mol
−
1
?
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