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Question

An ideal monoatomic gas is confined in a horizontal cylinder by a spring loaded piston (as shown in the figure). Initially the gas is at temperature T1, pressure P1 and volume V1 and the spring is in its relaxed state. The gas is then heated very slowly to temperature T2, pressure P2 and volume V2. During this process the piston moves out by a distance x. Ignoring the friction between the piston and the cylinder, the correct statement(s) is (are)

A
If V2=2V1 and T2=3T1, then the energy stored in the spring is 14P1V1.
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B
If V2=2V1 and T2=3T1 , then the change in internal energy is 3P1V1.
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C
If V2=3V1 and T2=4T1, then the work done by the gas is 73P1V1.
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D
If V2=3V1 and T2=4T1, then the heat supplied to the gas is 176P1V1.
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Solution

The correct options are
A If V2=2V1 and T2=3T1, then the energy stored in the spring is 14P1V1.
B If V2=2V1 and T2=3T1 , then the change in internal energy is 3P1V1.
C If V2=3V1 and T2=4T1, then the work done by the gas is 73P1V1.
We will assume that the gas on the side of container having spring is connected to atmosphere. Hence, its pressure remains constant at P1.
In final position of piston, force balance gives
Kx+P1A=P2A
where A = cross-sectional area of the piston.
So, Kx=(P2−P1)A (i)
Also,
P1V1T1=P2V2T2
If V2=2V1, T2=3T1, then P2=32P1
Also, V2−V1=Ax (ii)
(i) and (ii) give Kx=(P2−P1)(V2−V1)x∴12Kx2=12(P2−P1)(V2−V1) (iii)=12(P12)(V1)=P1V14
Hence (a) is correct.
ΔU=f2(P2V2−P1V1)=32(32×2P1V1−P1V1]=3P1V1
Hence, (b) is correct as well.
Net work done on piston by all forces is zero. So,
Wgas−12Kx2−P1(V2−V1)=0∴Wgas=P1V13+2P1V1Wgas=73P1V1
So, (c) also turns out be correct.

Q=ΔU+WΔU=32(P2V2−P1V1)=32(43P1.3V1−P1V1)⇒ΔU=92P1V1∴Q=92P1V1+73P1V1⇒Q=416P1V1
Hence (d) is not correct.

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