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Question

An ideal solution if obtained by mixing CH3CHBr2 and CH2Br−CH2Br in the ratio 2:1
PoCH3CHBr2=173,PoCH2BrCH2Br=127. Thus total vapour pressure is:

A
158
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B
257
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C
137
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D
197
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Solution

The correct option is A 158
P=Po1x1+Po2x2
x1=22+1=23
x2=13
Total pressure =P
Partial pressure of CH3CHBr2=Po1
Partial pressure of CH3BrCH2Br=Po2
Mole fraction CH3CHBr2=x1
Mole fraction CH3CHBrCH2Br=x2
P=173×23+127×13
P=158.

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