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Question

An industrial fuel, 'water gas', which consists of a mixture of H2 and CO can be made by passing steam over red-hot carbon. The reaction is:
C(s)+H2O(g)CO(g)+H2(g), ΔH= +131 kJ
The yield of the product can be increased by:

A
Adding of He(g) at constant pressure
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B
Adding hot carbon
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C
Raising the temperature
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D
Reducing the volume of the system
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Solution

The correct options are
A Adding of He(g) at constant pressure
C Raising the temperature
(a) He is an inert gas, adding inert gas at constant pressure will increase the volume of the system, which results in decrease in concentration. So according to Le Chatelier's principle, the reaction will shift in that direction where the number of gaseous moles are more. Hence, more product will be formed.
(b) Adding solids does not affect equillibrium.
(c) This is an endothermic reaction. So, the reaction will move forward on increasing temperature.
(d) Reducing volume will increase the concentration and hence reaction will move in the direction where the gaseous moles are less. Hence, in this case the reaction will move backwards.

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