An insoluble salt prepared by synthesis is
FeS
Synthesis reactions- In a synthesis reaction, two atoms or molecule interact to form a different molecule.
Explanation for correct option b): FeS is synthesized by heating iron and sulphur together.
Also, FeS is insoluble in water.
Explanation for incorrect options:
FeCl3, NaCl, and CaCl2 are soluble in water.
Hence, the correct option is (B) FeS