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Question

An insulated container of gas has two chambers separated by an insulating partition. One of the chambers has volume V1 and contains ideal gas at pressure P1 and temperature T1.


The other chamber has volume V2 and contain same ideal gas at pressure P2 and temperature T2. If the partition is removed without doing any work on the gas, the final equilibrium temperature of the gas in the container will be:

A
T1T2(P1V1+P2V2)P1V1T2+P2V2T1
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B
P5V1T1+P2V2T2P1V1+P2V2
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C
P1V1T5+P2V2T1P1V1+P2V2
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D
T1T2(P1V1+P2V4)P1V1T1+P2V2T6
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Solution

The correct option is D T1T2(P1V1+P2V2)P1V1T2+P2V2T1
Let the final temperature be T and n1 & n2 be the no. of moles of gas in each container

Using conservation of energy

(n1+2)CVT=n1CVT1+n2CVT2

(P1V1RT1+P2V2RT2)T=P1V1R+P2V2R

(P1V1T2+P2V2T1T1T2)T=P1V1+P2V2

T=T1T2(P1V1+P2V2)P1V1T2+P2V2T1

Hence, the correct option is A

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