An object is said to be in a state of free fall when:
When the only force acting on it is the weight of the object.
Freefall is any motion of a body where its weight is the only force acting upon it. A body in free fall experiences an acceleration equal to 'g'. Thus, falling through an atmosphere without a deployed parachute or lifting device is also often referred to as free fall.
Any acceleration not equal to g implies another force other than gravity is acting on the object.
A body thrown up moves away from the earth for some time, even in this case the only force acting on the body is gravitational force. Hence a freely falling body need not move towards the Earth.