MyQuestionIcon

1

You visited us 1 times! Enjoying our articles? Unlock Full Access!

Structural Isomerism

An octahedral...

Question

An octahedral complex with molecular composition $M .5 N H_{3} . C l . S O_{4}$ has two isomers, $A$ and $B$ . The solution of $A$ gives a white precipitate with $A g N O_{3}$ solution and the solution of $B$ gives white precipitate with $B a C l_{2}$ solution. The type of isomerism exhibited by the complex is:

A

linkage isomerism

No worries! We‘ve got your back. Try BYJU‘S free classes today!

B

ionisation isomerism

Right on! Give the BNAT exam to get a 100% scholarship for BYJUS courses

C

coordinate isomerism

No worries! We‘ve got your back. Try BYJU‘S free classes today!

D

geometrical isomerism

No worries! We‘ve got your back. Try BYJU‘S free classes today!

Open in App

Solution

The correct option is D ionisation isomerism
$A + A g N O_{3} \to (x) w h i t e$
White precipitate is $A g C l (x)$ .
$B + B a C l_{2} \Rightarrow (y)$
White precipitate is $B a S O_{4} (y)$ .

Hence, both ion which can be interchanged. Hence, ionisation isomerism is the correct option.

Suggest Corrections

thumbs-up

0

Similar questions

Q. The octahedral complex

C o S O_{4} C l_{5} N H_{3}

exists in two isomeric forms

X

Y

X

A g N O_{3}

to give a white precipitate, but does not react with

B a C l_{2}

Y

gives white precipitate with

B a C l_{2}

but does not react with

A g N O_{3}

X

Y

Q. The octahedral complex

C o S O_{4} C l .5 N H_{3}

exists in two isomeric forms X and Y. Isomer X reacts with

A g N O_{3}

to give a white precipitate, but does not react with

B a C l_{2}

. Isomer Y gives white precipitate with

B a C l_{2}

but does not react with

A g N O_{3}

. Isomer X and Y are

$C o S O_{4} C l .5 N H_{3}$ exists in two isomeric forms 'A and 'B'. Isomer 'A' reacts with $A g N O_{3}$ to give white precipitate, but does not react with $B a C l_{2} .$ Isomer 'B' gives white precipitate with $B a C l_{2}$ but does not react with $A g N O_{3} .$ Answer the following questions.
(a) Identify \A' and 'B' and white their structural formulae
(b) Name the type of isomerism involved.
(c) Give the IUPAC name of 'A' and 'B'.

Q. A coordination compound X gives pale yellow colour with

A g N O_{3}

solution while its isomer Y gives white precipitate with

B a C l_{2}

. Two compounds are isomers of

C o B r S O_{4}

5 N H_{3}

. What could be the possible formula of X and Y?

Q. An isomer of the complex

C o B r C l_{2} (e n)_{2} (H_{2} O)

, on reaction with concentrated

H_{2} S O_{4}

(dehydrating agent), suffers no loss in weight and on reaction with

A g N O_{3}

solution it gives only white precipitate, which is soluble in

N H_{3}

solution.

The correct formula of the complex is:

View More

Join BYJU'S Learning Program

similar_icon

Related Videos

lock

Structural Isomerism

CHEMISTRY

Watch in App

explore_more_icon

Explore more

Structural Isomerism

Standard X Chemistry

Join BYJU'S Learning Program

CrossIcon