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Question

An open flask contains air at 27oC. To what temperature it must be heated to expel one-fourth of the air?

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Solution

Initial temperature = 300 K
Let no. of a mole at 300K = n
Let new temperature be = T K

mole coming out at T K = 14 n

mole left at T K =n 14

=23 n

under constant p and v: n1T1=n2T2

n×300= 23n×T

T=450K

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