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Question

An open vessel containing air is heated from 300K to 400K. The fraction of air, which goes out with respect to originally present is:

A
3/4
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B
1/4
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C
2/3
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D
1/8
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Solution

The correct option is A 1/4
As the vessel is open, the pressure remains constant.
There is no change in the volume of the vessel. Hence, the volume also constant.
ACC to ideal gas equation, PV=nRT
n1+1T1=300K n2=?T2=400K
n1n2=T2T1 (At constant P,V)
1x=400300
Fraction of air present in vessel after heating =34.
Fraction of air getting out of the vessel =134=14

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