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Question

An organic acid 'X' is a liquid which often freezes during winter time in cold countries. It has the molecular formula C2H4O2 . On warming with ethanol in the presence of a few drops of sulphuric acid, a compound ‘Y’ with sweet smell is formed. (i) Identify X and 'Y'. (ii) Write chemical equation for the reaction involved

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Solution

The available information suggests that the organic acid X with molecular formula C2H4O2 is ethanoic acid (CH3COOH). It reacts with ethanol in the presence of a few drops of sulphuric acid to give ester, ethyl ethanoate which has a pleasant smell.
Hence X is CH3COOH or Acetic Acid and Y is CH3COOCH2CH3 or ethyl ethanoate.

Chemical Reaction:

CH3COOH + CH3CH2OH conc.H2SO4−−−−−− CH3COOCH2CH3 + H2O


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