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Question

An organic compound decolourises bromine in CCl4 and can be reduced catalytically. Also, it gives a precipitate with ammoniacal cuprous chloride. The compound can be:

A
CH3Ch=CHCH3
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B
CH3CH2CCH
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C
CH3CH=CH2
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D
CH3C|CH3=CH2
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Solution

The correct option is B CH3CH2CCH
Answer B.
The organic compound decolorises bromine in CCl4. Hence it is unsaturated compound, that is, it can be either alkene or alkyne.
Since, the given compound gives a precipitate with ammonical cuprous chloride, it should be an alkyne as alkenes do not react with ammonical cuprous chloride.
The compound is CH3CH2CCH.

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