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Question

An oxide of N has vapour density 46. Find the total number of electrons in its 92g.

A
46×6.023×1023 electrons
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B
46 electrons
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C
92×6.023×1023 electrons
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D
6.023×1023 electrons
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Solution

The correct option is A 46×6.023×1023 electrons
Let oxide of N be N2Om
Vapour density of N2Om=46 = molecularmassofgasmolecularmassofhydrogen
Molar mass of N2Om=2×46=92g mol1
2×14+m×16=92 or m=4
Oxide is N2O4
Now given 92g N2O4,i.e.,N molecules of N2O4
1 molecule of N2O4 has 46 electrons
N molecules of N2O4=46×N electrons
=46×6.023×1023 electrons

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