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Question

An oxide of nitrogen has a molecular weight of 92. Find the total no.of electrons in one gram mole of that oxide

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Solution

The atomic numbers of nitrogen and oxygen are one half their mass numbers. Hence, one molecule of compound having molecular weight of 92 will contain 46 electrons. So, 1 gram mole of molecule will contain 46N electrons. Here, N is the Avogadro number.

Explaining further,
For nitrogen,
Atomic number, Z = 7
Mass number , A = 14
Mass number / Atomic number = A/Z = 2.
For oxygen,
Z = 8
A= 16
A/Z = 2.
So an oxide of N, will only have N and O and hence the A/Z ratio of oxide will also be 2.
For oxide,
A/Z = 2
A = 92 (given)
Hence, Z = A/2 = 46.
We know,
Z is atomic number, which is number of protons. As oxides are neutral, Atomic number is same as number of electrons, = 46.
1 molecule of oxide has 46 electrons.
1 mole oxide has 1 N molecules, N= Avogadro number.
Hence 1 mole / gram mole oxide has 46 N electrons.
Hence, answer is 46N

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